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CARNOT'S DIFFICULTY WITH THE SECOND LAW



 
 
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Old August 31st 11, 09:59 AM posted to sci.astro,sci.math
Pentcho Valev
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Default CARNOT'S DIFFICULTY WITH THE SECOND LAW

In 1824 Sadi Carnot deduced the second law of thermodynamics from a
premise that went against the future law of conservation of energy
(the first law of thermodynamics). Here is an oversimplified but
consonant with the quotation below presentation of (part of) Carnot's
1824 argument:

Premise: Heat is an indestructible substance (caloric) that cannot be
converted into work by the heat engine.
Conclusion: A cold body accepting part of the heat taken from the warm
body NECESSARILY assist the heat engine.

Unpublished notes written in the period 1824-1832 reveal that, after
discovering the first law of thermodynamics (much earlier than the
official discovery), Carnot started to doubt the second:

http://www.nd.edu/~powers/ame.20231/carnot1897.pdf
p. 225: Sadi Carnot: "Heat is simply motive power, or rather motion
which has changed form. It is a movement among the particles of
bodies. Wherever there is destruction of motive power there is, at the
same time, production of heat in quantity exactly proportional to the
quantity of motive power destroyed. Reciprocally, wherever there is
destruction of heat, there is production of motive power."
p. 222: Sadi Carnot: "Could a motion (that of radiating heat) produce
matter (caloric)? No, undoubtedly; it can only produce a motion. Heat
is then the result of a motion. Then it is plain that it could be
produced by the consumption of motive power, and that it could produce
this power. All the other phenomena - composition and decomposition of
bodies, passage to the gaseous state, specific heat, equilibrium of
heat, its more or less easy transmission, its constancy in experiments
with the calorimeter - could be explained by this hypothesis. But it
would be DIFFICULT TO EXPLAIN WHY, IN THE DEVELOPMENT OF MOTIVE POWER
BY HEAT, A COLD BODY IS NECESSARY; why, in consuming the heat of a
warm body, motion cannot be produced."

I think that, almost 200 years later, Carnot's question is both
relevant and unanswered:

WHY, IN THE DEVELOPMENT OF MOTIVE POWER BY HEAT, A COLD BODY IS
NECESSARY; why, in consuming the heat of a warm body [in the absence
of a cold one], motion cannot be produced [in a cyclical process]?

Pentcho Valev

 




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