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Clifford Truesdell, The Tragicomical History of Thermodynamics, 1822-1854, p. 6: "Finally, I confess to a heartfelt hope - very slender but tough - that even some thermodynamicists of the old tribe will study this book, master the contents, and so share in my discovery: Thermodynamics need never have been the Dismal Swamp of Obscurity that from the first it was and that today in common instruction it is; in consequence, it need not so remain."
https://www.amazon.com/Tragicomical-.../dp/1461394465 Jos Uffink, Bluff your way in the Second Law of Thermodynamics: "Before one can claim that acquaintance with the Second Law is as indispensable to a cultural education as Macbeth or Hamlet, it should obviously be clear what this law states. This question is surprisingly difficult. The Second Law made its appearance in physics around 1850, but a half century later it was already surrounded by so much confusion that the British Association for the Advancement of Science decided to appoint a special committee with the task of providing clarity about the meaning of this law. However, its final report (Bryan 1891) did not settle the issue. Half a century later, the physicist/philosopher Bridgman still complained that there are almost as many formulations of the second law as there have been discussions of it. And even today, the Second Law remains so obscure that it continues to attract new efforts at clarification." http://philsci-archive.pitt.edu/313/1/engtot.pdf Is it true that thermodynamics is a "dismal swamp of obscurity" and that it is not clear what the second law of thermodynamics states? In the post-truth world questions starting with "Is it true that..." have a single universal answer: "Who cares." There is only one clear and unambiguous formulation of the second law of thermodynamics and it was given by Sadi Carnot himself: "A cold body is necessary" That is, heat cannot be cyclically converted into work unless some temperature gradient is present - a hot body, source of heat, and a cold body, receiver of heat, must be available. The problem is that in 1824 Carnot deduced "A cold body is necessary" from a postulate that eventually turned out to be false: Carnot's (false) postulate: Heat is an indestructible substance (caloric) that cannot be converted into work by the heat engine. Unpublished notes written in the period 1824-1832 reveal that, after realizing that his postulate was false, Carnot found "A cold body is necessary" implausible: http://www.nd.edu/~powers/ame.20231/carnot1897.pdf Sadi Carnot, REFLECTIONS ON THE MOTIVE POWER OF HEAT, p. 225: "Heat is simply motive power, or rather motion which has changed form. It is a movement among the particles of bodies. Wherever there is destruction of motive power there is, at the same time, production of heat in quantity exactly proportional to the quantity of motive power destroyed. Reciprocally, wherever there is destruction of heat, there is production of motive power." p. 222: "Could a motion (that of radiating heat) produce matter (caloric)? No, undoubtedly; it can only produce a motion. Heat is then the result of a motion. Then it is plain that it could be produced by the consumption of motive power, and that it could produce this power. All the other phenomena - composition and decomposition of bodies, passage to the gaseous state, specific heat, equilibrium of heat, its more or less easy transmission, its constancy in experiments with the calorimeter - could be explained by this hypothesis. But it would be DIFFICULT TO EXPLAIN WHY, IN THE DEVELOPMENT OF MOTIVE POWER BY HEAT, A COLD BODY IS NECESSARY; why, in consuming the heat of a warm body, motion cannot be produced." Generally, a cold body is not necessary, that is, the second law of thermodynamics is false. The cold body is only TECHNOLOGICALLY necessary as it makes heat engines fast-working. Heat engines working under isothermal conditions (in the absence of a cold body) are commonplace but are too slow and impuissant to be of any technological importance. Except, perhaps, for the case where water is placed in an electric field - the non-conservative force (pressure) that emerges between the cathode and the anode seems to be quite vigorous: http://farside.ph.utexas.edu/teachin...es/node46.html "However, in experiments in which a capacitor is submerged in a dielectric liquid the force per unit area exerted by one plate on another is observed to decrease... [...] This apparent paradox can be explained by taking into account the difference in liquid pressure in the field filled space between the plates and the field free region outside the capacitor." http://www.youtube.com/watch?v=T6KAH1JpdPg Liquid Dielectric Capacitor https://www.youtube.com/watch?v=17UD1goTFhQ "The Formation of the Floating Water Bridge including electric breakdowns" Pentcho Valev |
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