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VERSIONS OF THE SECOND LAW OF THERMODYNAMICS
The "entropy always increases" version of the second law of
thermodynamics was a conclusion deduced by Clausius from two false premises. Clausius eventually abandoned it but the enchanted scientific world did not: http://philsci-archive.pitt.edu/archive/00000313/ Jos Uffink, "Bluff your Way in the Second Law of Thermodynamics", pp. 39-40: "On many occasions Clausius was criticised by his contemporaries. I do not know if, in his own time, he was criticised in particular for his famous formulation of the second law as the increase of the entropy of the universe. However, Kuhn (1978, pp. 13-15, p. 260) has pointed out the remarkable fact that in the book (Clausius 1876) he eventually composed from his collected articles, every reference to the entropy of the universe and even to the idea that entropy never decreases in irreversible processes in adiabatically isolated systems is deleted!" Let us assume that Kelvin's version of the second law can be violated, that is, in some cases, heat can be converted into work cyclically and isothermally. Would there be respective violations of the "entropy always increases" version? Only if Clausius' deduction of the latter version is valid and based on true premises. If not, a scenario is conceivable in which violations of the second law do occur in nature but our entropic glasses prevent us from seeing them. In this scenario the "entropy always increases" version automatically becomes the red herring suggested by Ehrenfest-Afanassjewa and Uffink: http://philsci-archive.pitt.edu/archive/00000313/ Jos Uffink, "Bluff your Way in the Second Law of Thermodynamics", p. 94: "This summary leads to the question whether it is fruitful to see irreversibility or time-asymmetry as the essence of the second law. Is it not more straightforward, in view of the unargued statements of Kelvin, the bold claims of Clausius and the strained attempts of Planck, to give up this idea? I believe that Ehrenfest-Afanassjewa was right in her verdict that the discussion about the arrow of time as expressed in the second law of the thermodynamics is actually a RED HERRING." Pentcho Valev |
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