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#12
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George wrote:
However, the Muldraugh limestone in Elisabethtown, Kentucky contains huge gypsum nodules that were believed to be formed as a secondary replacement of smaller concretions. These gypsum nodules can be as big as 18" in diameter. All of the cave gypsum I have seen weas formed in a dry environment out of shale or shaley limstone with a high sulphate concentration. ditto the gypsum info. I think I'd go for oolitic hematite instead. That is certainly a possibility. Only I think what I saw with the TES map they made of the site was that the highest concentrations of hematite occurs outside of the crater. Of course, that doesn't entirely rule out the possibility of the spherules contain hematite. I guess we will have to wait for them to make another announcement. One thing though, and I ask this because although I am very familiar with Oolitic limestone formation (we have the St. Genevieve limestone in my neck of the woods too, and I've studied it for many years), I don't know much about oolitic hematite other than it does occur. Does oolitic hematite form in the same way that carbonate oolites form? If so, they would have to accrete by rolling around on the floor of come bldy of water dure to current agitation, would they not? I'm not saying that this isn't a possibility at the rover landing site, I'm just trying to get a clearer picture of how hematite oolites form. Can they form by replacement of the original carbonate with hematite by percolation of iron-rich ground water? I don't know if this is a possibility, but I do know that ground water in many water wells in Kentucky and Southern Indiana that are completed in the St. Genevieve limestone have a high iron content, yet I have never seen oolites in the St. Genevieve that were replaced with hematite. That goes for the Illionois Fluorspar district as well. I've never seen hematite oolites there either, even though the iron content of the ground water there is high. I guess it may be a question of the high Ph water keeping the iron in solution. What say you? I'm going to say something we rarely hear around he I don't know the mechanism of hematite oolite formation, and don't think I have the resources around here to find out. The occurrences I know of are in hydrothermal igneous settings, and are only sedimentary in the sense they have been concentrated by either reheating or dissolution. |
#13
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![]() "Jo Schaper" skrev i en meddelelse ... snip I'm going to say something we rarely hear around he I don't know the mechanism of hematite oolite formation, and don't think I have the resources around here to find out. The occurrences I know of are in hydrothermal igneous settings, and are only sedimentary in the sense they have been concentrated by either reheating or dissolution. I'll dare to jump into the discussion with a proposal of the spheres as primary precipitation like the manganes nodules. Such a point takes a consideration as to the apparent non-disturbance of the layers where they grow, as this is the argument that NASA highlights in their proposal. My argument may be thin, but it has advantages: the nodules are round and settling sediment 'fall off', or just does not 'grow' on the spheres if the parallel-lamina are evaporites that develope on the sediment/water-interface. As far as I know, the manganese nodules stays on top of the sediment/water-interface - and I get it as reducing conditions below this interface may dissolve the nodules and the dissolved solution may reprecipitate. I'm no expert on manganese-nodules, but if abiogen conditions apply (read: no reduction-potential), then the nodules may ramain in the sediment. As 'bigdakin' might say: 'I just throw it at the wall to see if it sticks'. Carsten |
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