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In my previous posts on the run-away greenhouse (which we know must
have happened to Venus some time in its past), I have assumed that liquid water would disappear when the surface temperature reached the critical point (705 degrees F). This is not true, though, because of the presence of salts which will raise the critical point beyond any reasonable surface temperature [1] causing the last parts of the ocean to remain liquid as long as the atmosphere is near saturated with water vapor, which it will be until almost all the water is lost to space. When this occurs there should remain large deposits of salts on the surface. Now though Venus has HCl in its atmosphere, it is only a small fraction (10^-4) of the amount that must have existed in its oceans. So where is all the salt on Venus? Obviously, it is thought that Venus underwent complete resurfacing ~700 my, which must have been later than losing its water. Therefore there need be no large salt deposits today, but it would still be interesting to now where the halogens go in the absence of water; they are still largely incompatible elements. [1] There is probably no limiting critical point, and salts and water have then a continuous critical curve, but that can never be determined in the laboratory. Not only NaCl, but I don't know any salts that have a low enough critical point for observation and do not decompose or react with water below that temperature. Andrew Usher |
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