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Old September 30th 17, 01:04 PM posted to sci.astro
Pentcho Valev
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Default Thermodynamics: Dismal Swamp of Obscurity

Jos Uffink, Bluff your way in the Second Law of Thermodynamics: "I therefore argue for the view that the second law has nothing to do with the arrow of time. [...] Before one can claim that acquaintance with the Second Law is as indispensable to a cultural education as Macbeth or Hamlet, it should obviously be clear what this law states. This question is surprisingly difficult. The Second Law made its appearance in physics around 1850, but a half century later it was already surrounded by so much confusion that the British Association for the Advancement of Science decided to appoint a special committee with the task of providing clarity about the meaning of this law.. However, its final report (Bryan 1891) did not settle the issue. Half a century later, the physicist/philosopher Bridgman still complained that there are almost as many formulations of the second law as there have been discussions of it. And even today, the Second Law remains so obscure that it continues to attract new efforts at clarification." http://philsci-archive.pitt.edu/313/1/engtot.pdf

As Clifford Truesdell suggests, the confusion started with Clausius's 1850 idiotic argument - later formulations of the second law of thermodynamics have all been defective. However previous formulations - those of Carnot - were both clear and correct. The simplest one is this:

"A cold body is necessary"

That is, heat cannot be cyclically converted into work unless a hot body, source of heat, and a cold body, receiver of heat, are available. The problem is that in 1824 Carnot deduced "A cold body is necessary" from a postulate that eventually turned out to be false:

Carnot's (false) postulate: Heat is an indestructible substance (caloric) that cannot be converted into work by the heat engine.

Unpublished notes written in the period 1824-1832 reveal that, after realizing that his postulate was false, Carnot found "A cold body is necessary" implausible:

Sadi Carnot, REFLECTIONS ON THE MOTIVE POWER OF HEAT, p. 225: "Heat is simply motive power, or rather motion which has changed form. It is a movement among the particles of bodies. Wherever there is destruction of motive power there is, at the same time, production of heat in quantity exactly proportional to the quantity of motive power destroyed. Reciprocally, wherever there is destruction of heat, there is production of motive power." p. 222: "Could a motion (that of radiating heat) produce matter (caloric)? No, undoubtedly; it can only produce a motion. Heat is then the result of a motion. Then it is plain that it could be produced by the consumption of motive power, and that it could produce this power. All the other phenomena - composition and decomposition of bodies, passage to the gaseous state, specific heat, equilibrium of heat, its more or less easy transmission, its constancy in experiments with the calorimeter - could be explained by this hypothesis.. But it would be DIFFICULT TO EXPLAIN WHY, IN THE DEVELOPMENT OF MOTIVE POWER BY HEAT, A COLD BODY IS NECESSARY; why, in consuming the heat of a warm body, motion cannot be produced."
http://www.nd.edu/~powers/ame.20231/carnot1897.pdf

Generally, a cold body is not necessary, that is, the second law of thermodynamics is false. The cold body is only TECHNOLOGICALLY necessary - such heat engines are fast-working and powerful. Heat engines working under isothermal conditions (in the absence of a cold body) are commonplace but are too slow and impuissant to be of any technological importance. Except, perhaps, for the case where water is placed in an electric field - the non-conservative force (pressure) that emerges seems to be able to convert ambient heat into work quite vigorously:

"However, in experiments in which a capacitor is submerged in a dielectric liquid the force per unit area exerted by one plate on another is observed to decrease... [...] This apparent paradox can be explained by taking into account the DIFFERENCE IN LIQUID PRESSURE in the field filled space between the plates and the field free region outside the capacitor."
http://farside.ph.utexas.edu/teachin...es/node46.html

"Liquid Dielectric Capacitor" http://www.youtube.com/watch?v=T6KAH1JpdPg

"The Formation of the Floating Water Bridge including electric breakdowns"
https://www.youtube.com/watch?v=17UD1goTFhQ

Pentcho Valev